5. June 2020

Opposing Phase-Segregation and Hydrogen-Bonding Forces in Supramolecular Polymers.

Chen, S., et al. Angewandte Chemie International Edition 2017, 56 (42), 13016-13020, DOI:

We report significant changes in the association behavior of covalent H-bonds by the phase of attached polymer chains. Depending on the aggregation state, we observed either intact H-bonds despite segregation of the phases, or macrophase separation with a larger amount of H-bonding dissociation. Reproduced with permission. Copyright 2017©, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.